Despite repeated appeals by both clubs for their fans to behave during the week, violent skirmishes were reported in the build-up to a game which Schalke won 2-1 in Dortmund.
This comes after some high profile recent supporter incidents, including Serbian fans racially abusing England U21 players and a Leeds fan smacking Sheffield Wednesday goalkeeper Chris Kirkland in the face.
Confrontation: Dortmund fans face riot police before the game
One police car was damaged as mounted police, riot police and agents with dogs were brought in to keep the spectators apart.
Flare up: Smoke fills the stadium
Mounted police were 'attacked by Dortmund hooligans with cobble stones', according to a police report.
The first reports of trouble were circulated almost three hours before kick-off when 'a group of around 100 masked Schalke fans left the underground station and went on the rampage, lighting flares on their way towards the stadium'.
'This has nothing to do with football supporters and we don't want to see them in Dortmund,' said the Dortmund police chief director Dieter Keil.
Face off: Fans stand before the police
The culprits were all caught on video, however, and will be prosecuted, according to the police statement.
Victory: Schalke celebrate their win
Disturbances were kept to a minimum after the game with the police successfully able to keep both sets of fans apart.
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